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  • One aspect of the invention is a pharmaceutical composition comprising a metal-binding, polycarboxylated porphyrin in unit dosage and a pharmaceutically acceptable excipient, wherein the porphyrin has structure I, wherein the eight R?? positions and the four Rm positions are independently H, lower alkyl, lower alkyloxyl, or lower alkylcarboxyl, wherein at least one R?? position at each pyrrole is
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